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Sulphuric Acid on the WebTM Technology Manual DKL Engineering, Inc.

Knowledge for the Sulphuric Acid Industry
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Introduction
General

Definitions
Instrumentation
Plant Safety
Metallurgial Processes
Metallurgical
Sulphur Burning
Acid Regeneration
Lead Chamber
Technology
Gas Cleaning
Contact
Strong Acid
Acid Storage
Loading/Unloading

Transportation
Sulphur Systems
Liquid SO2
Boiler Feed Water
Steam Systems

Cooling Water
Effluent Treatment
Utilities
Construction
Maintenance
Inspection
Analytical Procedures
Materials of Construction
Corrosion
Properties
Vendor Data

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Maintenance and Inspection - Pump Tanks
September 15, 2003

Introduction
Shell Corrosion
Floor Lifting
Shell Bulging
Associated Links

Pressure Grouting

Materials of Construction

Acid Resistant Linings


Introduction

Shell Corrosion

The brick lining in this pump tank has been compromised such that the acid has leaked through the brick lining to the carbon steel shell.  The carbon steel shell has corroded completely through exposing the sulphate that has built up between the brick and the shell.

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Floor Lifting

When acid penetrates through the brick lining of a flat bottom pump tank, the carbon steel shell will corrode resulting in sulphate formation.  The sulphate formed occupies a greater volume than the parent material and begins to exert pressure on the shell and the brick lining.  One of two things can happen: the brick floor heaves upward or the flat bottom begin to bulge.  In the pump tank pictured here, the bottom has begun to bulge causing the edges of the pump tank to lift off the support grillage.

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Shell Bulging

Acid that has penetrated the wall lining will attack the carbon steel shell and form sulphate between the shell and brick.  The pressure that builds up usually cannot push the bricks out because they are in compression.  The only release for the pressure build up is to cause the carbon steel shell to bulge outwards as seen in the picture.

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