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DKL Engineering, Inc.
		
Handbook of Sulphuric Acid Manufacturing
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		Preface
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Sulphuric Acid 
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Preface
Contents
Steam Systems - Economizers
September 17, 2001
| 
	Introduction Steaming Gas Temperature Control Parallel vs. Series Boiler Feed Water Preheating Gas Dew Point Temperature Tube Wall Temperature  | 
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Economizers 
serve to improve the efficiency of plant operation by recovering waste heat from 
the gas stream an putting the energy into generating steam.
If steaming occurs in an 
economizer not designed to generate steam, water hammer and vibration may 
result.  These problems can be avoided by not designing for too close an 
approach to the saturation temperature in the economizer.
If steaming cannot be 
avoided, the economizer can be designed to ensure the steam/water mixture flows 
upward through the bundle and into the steam drum.  This avoids high points 
where the steam can separate from the mixture and give rise to hydraulic 
disturbances.
To prevent condensation of 
acid on the shellside it is preferable to bypass on the water side to control 
the gas exit temperature.  Any reduction in gas flow due to gas bypassing 
results in a closer temperature approach at the exit of the economizer and 
increased chance of condensation.  Depending on the degree of 
instrumentation and automation, the bypass can either be a manual valve or a 
control valve.
In a double absorption plant, economizers can be placed prior to the 
Intermediate and Final Absorber Towers to cool the gas before it enters the 
towers.  When there are more than two economizers a decision must be made 
as to whether to place the units in parallel or series with respect to the water 
side.
In the example given (ie. double absorption plant) it is preferable to place the 
economizers in series on the water side with the boiler feed water entering the 
'Final' economizer first and then the 'Inter' economizer.  This arrangement 
reduces the chance of condensation in the economizers.
Boiler feed water typically leaves the deaerator at 105°C (221°F).  At this 
temperature there is a strong possibility that the tube wall temperature will be 
low enough that condensation will occur on the shell side.  The dewpoint of 
the gas entering the Intermediate Absorber is expected to be higher than the gas 
entering the Final Absorber.  In this arrangement the coldest boiler feed 
water is first fed through the unit ('Final' economizer) where condensation is 
least likely to occur.  The boiler feed water leaves the 'Final' 
economizers preheated before it enters the 'Inter' economizers.  The result 
is a higher tube wall temperature in the 'Inter' economizer and condensation of 
acid is less likely to occur.
Preheating the boiler feedwater can help reduce the possibility of condensation 
on the shell side of economizers by raising the tube water temperature above the 
dewpoint of the gas.  This can be done in a number of ways such as 
increasing the deaerator operating temperature, heat recovery from blowdown, 
attemporators, steam desuperheating, etc.  These and other techniques are 
discussed in more detail in BFW Heating Systems.  
The disadvantage of using hotter boiler feed water is a closer temperature 
approach at the gas outlet/water inlet of the economizer which increases its 
size.  However, the size increase can probably be tolerated by the fact 
that condensation has been avoided.
There are several techniques that can be used within the economizer itself to 
raise the tube wall temperature.  The simplest is to design the economizer 
as a co-current instead of a countercurrent exchanger.  The disadvantage is 
the unit is much bigger when designed as a co-current unit rather than a 
countercurrent unit.
An alternative is to place a small bank of tubes at the gas inlet in which the boiler feed water is preheated before entering the primary tube bundle in countercurrent flow to the gas.
If process gas is cooled 
down far enough, acid will condense from the gas onto the cold surface.  
The temperature at which condensation begins is called the dew point 
temperature.   The dew point of the gas is a function of the partial 
pressure of water and sulphur trioxide in the gas.  The SO3
in the gas comes as a result of the conversion of SO2 
to SO3.  Water enters the plant from the 
small amount that is not removed in the dry tower or from the combustion of 
hydrocarbons in sulphur.
As the partial pressure of either component is raised, the dew point temperature increases. Several methods are available to estimate the dew point of the gas. Unfortunately, the dew points obtained from the different methods may vary by more than 20°C.
Condensation will occur on a cold surface if its temperature is low enough. In an economizer, the section of tubes which sees the coldest gas will be most prone to condensation on the surface of the tube. Because of thermal resistances in the surface films and tube wall, the temperature of the tube surface will be inbetween the temperature of the water and gas. The tube wall temperature should be checked to ensure condensation will not occur.