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Sulphuric Acid on the WebTM Technology Manual DKL Engineering, Inc.

Knowledge for the Sulphuric Acid Industry
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Introduction
General

Definitions
Instrumentation
Plant Safety
Metallurgial Processes
Metallurgical
Sulphur Burning
Acid Regeneration
Lead Chamber
Technology
Gas Cleaning
Contact
Strong Acid
Acid Storage
Loading/Unloading

Transportation
Sulphur Systems
Liquid SO2
Boiler Feed Water
Steam Systems

Cooling Water
Effluent Treatment
Utilities
Construction
Maintenance
Inspection
Analytical Procedures
Materials of Construction
Corrosion
Properties
Vendor Data

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Sulphuric Acid Plant Safety - Vanadium Pentoxide Catalyst
Februrary 26, 2002

Introduction
Health Effects
Precautionary Measures When Handling
First Aid Procedures
Emergency Procedures
Personnel Protection Measures
Disposal Methods
Associated Links

Catalyst Unloading
Catalyst Loading

BASF
Monsanto Enviro-Chem Systems, Inc.
Haldor Topsoe


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Typical vanadaium pentoxide catalyst contain the following substances:

  • Diatomaceous Earth (Amorphous Silica)
  • Crystalline Silica
  • Quartz
  • Vanadium Salts
  • Sodium Salts
  • Potassium Salts 

Health Effects

  • Causes eye, skin and respiratory tract irritation

  • Repeated and prolonged inhalation can cause delayed lung damage

  • Suspected cancer hazard

  • Contains quartz which may cause cancer

Precautionary Measures When Handling

  • Avoid contact with eyes, skin and clothing

  • Avoid breathing dust

  • Keep containers closed

  • Use with adequate ventilation

  • Wash thoroughly after handling

First Aid Procedures

Eye Contact Immediately flush with lots of water for at least 15 minutes.  Obtain medical attention immediately.
Skin Contact Immediately flush with lots of water.  Remove contaminated clothing.  Obtain medial attention immediately.  Used clothing should be disposed of properly or washed before reusing.
Inhalation Remove to fresh air.  If not breathing give artifical respiration.  Give oxygen if breathing is difficult.  Obtain medical attention immediately.

Emergency Procedures

Spill or Leak Shovel the bulk of the material into a steel drum.  Sweep up the remaining material.  Wash down the area of the spill.  Wash water should be contained and disposed of properly. 

Personnel Protection Measures

Eye Protection Wear chemical goggles and have an eye wash station available.
Skin Protection Wear chemical resistant gloves and clothing to protect exposed skin.  Disposable clothing is preferable to cleaning and reusing clothing.
Respiratory Protection Avoid breathing dust.  Use NIOSH/MSHA approved respiratory protection equipment.
Ventilation Provide natural or mechanical ventilation to control exposure levels.

Disposal Methods

Waste or used catalyst should be disposed of in an approved chemical landfill in accordance with all applicable local, provincial, state and federal laws and regulations.  Metal reclaimers are available to recover vanadium pentoxide V2O5 from waste material.

 

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