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| Sulphuric Acid on the WebTM | Technology Manual | DKL Engineering, Inc. |
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Knowledge for
the Sulphuric Acid Industry Introduction
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In 1906, Dr. Frederick Cottrell, a professor of physical chemistry at Berkeley, successfully precipitated sulphuric acid fumes in a small electrostatic precipitator (ESP) test unit through the use of a high voltage transformer and the newly-invented synchronous mechanical rectifier. In 1907, Dr. Cottrell and his associates formed the International Precipitation Company for the marketing of his newly invented electrostatic precipitation process. Western Precipitation (WP) was established as a licensee for commercializing the ESP in the state of California. Dr. Cottrell's intent was to establish similar operating companies throughout the Unites States and Canada and then around the world. The commercial feasibility of the electrostatic precipitator was first demonstrated at a sulphuric acid plant of E.I. DuPont de Nemours Powder Works in Pinole, California, on the San Francisco Bay, where arsenic vapors were impacting the operation of their catalytic converters. The Western Precipitator ESP proved to be the effective solution and with its success, a second installation at the Selby Smelter followed that same year. This installation was designed for the collection of sulphuric fumes escaping from the gold smelting drums and remained in operation for several decades. The ESP was also
successfully demonstrated at the Riverside Cement Company in Crestmore, California for the
recapture of cement kiln dust. In 1912, Dr.
Cottrell with the other international patent holders, Sir Oliver Lodge of England and Dr.
Erwin Moeller of Germany, formed the Research Company as a non-profit patent
administrative company in the interest of developing the electrostatic precipitation
process worldwide. This organization acted as a clearinghouse for process
improvements and established operating territories for the participating companies, which
included Western Precipitation of Los Angeles, Research Corporation of New York,
Lodge-Cottrell of England, Lurgi Apparatebau- Gesellschaft of Germany and Japanese
Cottrell Corp. of Japan. This international cooperative provided for the accelerated development of the process until World War II when it was disbanded. Western Precipitation, Research Corporation and Lodge-Cottrell, Ltd continued their relationship until the United States government declared that the patent control and the territory distribution violated the Anti-Trust Laws. Consequently, Western Precipitation and Research Corporation entered into a Consent Decree in 1946, under which all territory restrictions were abrogated. Western Precipitation was then free to operate throughout the world. Western Precipitation was acquired by and became a division of the Joy Manufacturing Company in 1959, where it continued as the world leader in air pollution control technologies, offering a wide range of products for utility and industrial applications in the world marketplace, including Electrostatic Precipitators, Baghouses, Dry FGD systems using NIRO Atomizer technologies, Wet FGD systems, Multiclones and small scrubbers. In 1987, Ecolaire's
parent, Ecolaire Holding, merged with Joy Manufacturing Company, leaving Ecolaire as a
subsidiary of Joy Technologies Inc. Western Precipitation combined operations
with Allen-Sherman-Hoff (A-S-H), another Joy unit, forming Joy Environmental Technologies,
Inc. (JET). In 1994, Harnischfeger Industries acquired the stock of Joy Technologies and Joy became a subsidiary of Harnischfeger. In the following year, the Diamond Power Specialty Company, a division of the Babcock and Wilcox Company, a McDermott company, inquired as to the purchase of Joy Environmental Technologies, Inc., anticipating a synergy with its highly successful sootblower and auxiliary boiler equipment business. Following negotiations, Diamond Power Specialty Company (DPSC) acquired the assets of JET on December 20, 1995. Electrostatic precipitators use electrostatic forces to separate particles from the gas. The discharge electrode, which is normally negatively charged, emits a stream of electrons in the direction of the collecting electrode, which is at zero potential (i.e. earthed). The applied high voltage of 40 to 70 kV is responsible both for the development of the corona and the formation of the electric field between the electrodes. In the vicinity of the discharging corona the gas becomes ionized. The particles to be separated from the gas, which initially are at different potentials (positive, negative, neutral) are negatively charged because of the bombardment by negative ions and ionic diffusion. In the presence of the electric field the negatively charged particles begin to migrate to the collecting electrode. This migration is impeded by the viscosity of the gas but the electrostatic forces are strong enough to overcome the drag of the gas and the particles proceed to be collected. The efficiency of an electrostatic precipitator is given by the Deutsch equation:
where
The migration velocity is the average velocity at which the charged particle travels to the collecting electrode. The amount of electrical charge that can be place onto a particle is a function of the size of the particle, gas properties, electrical, chemical and physical properties of the particle as well as the design of the discharge electrode. The migration velocity is generally based on experimental and actual operating data determined from years of experience. Each vendor will have their own database of design velocities which they use when sizing their units. The magnitude of the migration velocity indicates the difficulty of removal for a particular contaminate. In general, acid mist, copper, iron and nickel are wasy to collect. Zinc, lead, arsenic and antimony are more difficult to collect. For a given gas velocity through the ESP the desired collection efficiency and migration velocity will set the collection area required. A simple and quick means of determining the performance of a ESP is to check the clarity of the gas leaving the ESP. Most ESP's are equipped with two sight glasses located 180° apart at the exit of the ESP which can be used to check the clarity of the gas. If present, acid mist will appear as a fog. If the operator can see clearly across the gas to the opposite side of the unit, the gas is considered optically clear. This will correspond to an acid mist loading of less than approximately 30 mg/Nm³ (0.84 mg/SCF). When designing a ESP, an acid mist loading of half this value 15 mg/Nm³ (0.42 mg/SCF) is generally used. All ESP's have basically the same components regardless of the vendor. The ESP's may look all different but they will all have the following components:
Examples of ESP installations from the different vendors is shown below. The picture in the introduction represents a typical Joy Technologies installation. Joy no longer exist as a company but their technology has been carried on by some vendors.
The design of the discharge electrode is one of the major features of an ESP that distinguishes one vendor from another. The discharge electrode must have the following properties to function effectively:
The sharp points or edges are required for the discharge corona to form. Early ESP's were used star wires which were lead covered wires made of steel or alloy 20. The cross-section of the wire is a multi-pointed star shape. The points form a continuous sharp edge running the length of the wire. The wire is support from the upper frame and held taught and straight by a lead weight at the bottom. The grooves running the length of the wire are susceptible to fouling if the units are not regularly flushed and maintained. Occasionally a wire would break and fall to the bottom of the unit. The worst case would be a broken wire that remains hung up in the tube causing an electrical short which would disable the entire unit. Research into the design and electrical discharge characteristics of the electrodes has resulted in a variety of different designs. The tendency is towards a rigid pole or mast with spikes which is offered by most vendors. The discharge electrode is held at both ends by the support frame on top and the guide frame on the bottom. Both frames are held in position by support insulators attached directly to the shell of the ESP. This ensures that the discharge electrode is always centred.
Electrostatic precipitators come in two basic styles; Plate and Tubular. The majority of wet ESP's are of the tubular design with only a fraction being of the plate design. The traditional style of tube is the circular tube. Early research into electrostatic precipitation determined that the optimum tube diameter was 250 mm (10 in.) This dimension is still the standard for tube size. Many different tube shapes are available each having advantages and disadvantages.
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Copyright© 2005,
2006, 2007, 2008 DKL
Engineering, Inc., All Rights Reserved |
