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Knowledge for
the Sulphuric Acid Industry Introduction
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Pure sulphuric acid is colourless or "water white". However, the presence of small amounts of organic material, will discolour the acid. These may be present in the incoming gas and are not totally removed in the gas cleaning section of the plant. The degree of discolourization varies from a
light brown to black depending on the quantity of organic matter. This colour would make an otherwise good quality
acid sell at a discounted price or not at all. An arbitrary standard scale is used as a means for matching of colour intensity. A colour of 5 units means that the intensity of the colour of this sample is equal to the intensity of the colour of a sample of sulphuric acid 50% in water, containing 5 milligrams of platinum (as potassium chloroplatinate) per liter. Blending of acid is of limited effectiveness
in improving the colour of the acid due to the large amount of colourless acid required to
achieve an acceptable product quality. Hydrogen peroxide (H2O2)
is effective in removing colour from the acid and the rate at which hydrogen peroxide
clears up the acid varies with the acid temperature, the quantity of SO2
dissolved in the acid and the strength of H2O2. Bench scale test should be performed to
determine the amount of hydrogen peroxide to be added, the temperature and residence
required to produce a product acid of acceptable quality.
Based on the results of the testing, bleaching
system can be designed based on conservative design parameters. One acid producer found that to reduce the
product acid colour to acceptable levels required between 0.5 to 1.4 kg of 50% H2O2
per metric tonne of 98% H2SO4 at an operating temperature of 80ºC. The residence time required for the reaction to
take place was 2 hours. A conservative design
of a bleaching system based on these test results would be for double the dosing rate and
a residence time of 4 to 5 hours.
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2006, 2007, 2008 DKL
Engineering, Inc., All Rights Reserved |