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Sulphuric Acid on the WebTM Technical Manual DKL Engineering, Inc.

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Sulphuric Acid Plant Specifications
 

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Acid Plant Database July 16, 2010

Owner Nyrstar

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Location PO Box 219
Ellen Street
Port Pirie SA 5540
Australia
Background Formerly
- The Broken Hill Assoc. Smelters Pty Ltd.
- Pasminco
- Zinifex
2007 -
Nystar today announced that as of 31 August 2007 it had taken ownership of the zinc and lead smelting and alloying assests of Umicore and Zinifex, thereby formally launching the company and creating the world’s largest zinc producer.
Website www.nyrstar.com
Plant -
Coordinates 33º 9' 58" S, 138º 0' 38" E
Type of Plant Metallurgical
Gas Source Pb
Sinter Machine
Plant Capacity 350 MTPD
SA/DA -
Status Operating
Year Built -
Technology -
Contractor -
Remarks -
Pictures   Nyrstar - Port Pirie 2.jpg (12649 bytes)  Nyrstar - Port Pirie 3.jpg (23880 bytes)  Nyrstar - Port Pirie 4.jpg (43220 bytes)  Nyrstar - Port Pirie 5.jpg (16113 bytes)  

Nyrstar - Port Pirie 6.jpg (34423 bytes)  Nyrstar - Port Pirie 7.jpg (55587 bytes)  Nyrstar - Port Pirie 8.jpg (38587 bytes)  Nyrstar - Port Pirie 9.jpg (40139 bytes)

General Port Pirie is an integrated multi metal smelter and refinery with flexibility to efficiently process a wide range of lead-dominant feedstocks.  Its products include refined lead and lead alloys, silver, zinc, copper, gold and sulphuric acid.  Port Pirie is located on the eastern shore of Spencer Gulf, South Australia and its operations and residue stockpiles are located on site. There is an adjacent dedicated port facility and products are dispatched by road and rail.
The smelter was built in 1889 for processing early Broken Hill lead concentrates. Since then it has been progressively upgraded and is now the largest primary lead smelter in the world. Currently, its blast furnace limits its capacity to approximately 245,000 tonnes per year, however, other parts of the facility have a capacity of approximately 270,000 tonnes. The current zinc and copper production facilities were commissioned in 1967 and 1984 respectively and the lead smelter in which gold and silver are largely recovered was rebuilt in 1998.
Port Pirie leases and operates the adjacent port facility from the Flinders Ports Corporation under a long-term arrangement. It operates a concentrate and residue unloading facility as well as the finished metal product and acid loading facility.
Port Pirie's strategy is to build on its scale and product flexibility, while continuing to meet the cost of sustaining its process plant and infrastructure. It intends to achieve this through diversifying its concentrate supply sources, expanding its production of high value metals, accelerating recovery of the zinc metal contained in current and historic residues and reducing its working capital and operating costs.

Process

Lead sulphide concentrates are sintered at high temperature into a lump form or sinter. Sulphur is oxidised to sulphur dioxide in a gas stream that is cleaned and processed to make sulphuric acid.  The sinter and coke are charged to a lead blast furnace that produces a crude lead bullion and slag and the bullion is then refined to remove impurities including copper, arsenic, antimony, bismuth, silver and gold.  Metallic copper is then produced through leaching, solvent extraction and electrowinning. Silver and gold are produced as refined and semi-refined products, respectively.  The blast furnace slag is fumed to recover zinc and lead as impure oxides. These oxides are then processed by leaching, solution purification and electrowinning to make market zinc metal, in a similar manner to the RLE process.

Operations

Although historically the majority of concentrates were sourced from the Broken Hill and Endeavour mines, the reduced availability of Broken Hill concentrates in recent years has led to an increase in supply from other sources, most notably Cannington, Rosebery and Century.  Currently, Port Pirie processes all of Rosebery's lead concentrates and a significant proportion of Century's lead concentrates.  In addition to processing lead concentrates, Port Pirie also processes around 110,000 tonnes of by-product residues which it sources from Hobart and from its own historic stockpiles.  The residues provide Port Pirie with an almost costless source of feedstock which contains over 17% zinc.  Currently, Port Pirie's capacity limits the quantity of residues it can treat and the excess received from Hobart is stockpiled on site. Plans to increase Hobart's proportion of Century concentrate are key to ensuring Port Pirie is able both to treat Hobart's residues and meet the EPA's target to eliminate all on site residue stockpiles by 2020.

Production

Following an improvement program that targeted plant availability and operating efficiency, Port Pirie's lead production capacity was approximately 270,000 tonnes peryear. The closure of the Cockle Creek smelter in 2003, however, removed Cockle Creek bullion as a feedstock, effectively limiting the plant capacity to 245,000 tonnes. Zinifex is currently evaluating a number of options to increase the blast furnace capacity.   The current zinc production facilities have a capacity of 43,000 tonnes per year of SHG and zinc alloys, which is fully utilised. Port Pirie produces approximately 95,000 tonnes per year of sulphuric acid, which is sold to a global acid marketing company under a long-term contract.

Environmental Management

Port Pirie works closely with and supports the local Environmental Health Centre to minimise potential health impacts of metals in the community. Community lead in blood levels in children are now at less than half the level that they were in the mid 1980's. Our aim is to progressively reduce lead in blood levels such that ultimately all children meet the national goal of 10 micrograms per decilitre.

References -
News -

MTPD - Metric Tonne per Day           STPD - Short Ton per Day
MTPA - Metric Tonne per Annum      STPA - Short Ton per Annum
SA - Single Absorption
DA - Double Absorption
 

* Coordinates can be used to locate plant on Google Earth