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Sulphuric Acid on the WebTM Technical Manual DKL Engineering, Inc.

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Sulphuric Acid on the Web

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Handbook of Sulphuric Acid Manufacturing
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Sulphuric Acid Plant Specifications
 

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Acid Plant Database October 18, 2010

Owner The Doe Run Company

doerunlogo.jpg (6487 bytes)

Location 881 Main Street
Herculaneum, Missouri
63048 USA
Background Formerly
- St. Joseph Lead Company (St. Joe Minerals Corp.)
- Doe Run Corp. formed by a joint venture between St. Joseph Lead Co. and Homestake Mining
(AMAX Lead Company of Missouri, Manger for AMAX-Homestake Lead Trollers)
- The Renco Group purchased Doe Run in 1994
Website www.doerun.com
Plant Herculaneum Smelter
Coordinates 38º 15' 37" N, 90º 22' 37" W
Type of Plant Metallurgical
Gas Source Lead (Pb)
Sinter Machine
Plant Capacity 180 MTPD
SA/DA 4 SA
Emissions SO2: 20,000 lb/h from all sources
         (6 lb/h attributed to SO2 sources that do not emit through the main stack)
         (19,994 lb/h attributed to SO2 sources that emit through the main stack)
Sulphuric acid plant tailgas discharges through main stack so acid plant emission is not regulated separately
Status Operating
Year Built 1968
Technology Chemical Construction Company - Chemico
Contractor Chemical Construction Company - Chemico
Remarks -
Permits State of Missouri Department of Natural Resources
Facility ID: 099-0003
Part 70 Permit to Operate
Permit No. Issue Date Expiration Date Date Modified
OP2006-011B December 17, 2007 December 16, 2012 -
- - - -
Pictures  
General -
References Missouri Permit No. OP2006-011B
News

October 12, 2010 - The Doe Run Lead company plans have a new, cleaner, smelter in operation in about three years. A company spokesman says Doe Run is looking for ways to finance the $150 million plant will not release lead, carbon dioxide, or sulfur dioxide into the air.  The announcement has come a week after the company agreed with federal regulators to spend $65 million to fix environmental problems at Doe Run and eventually close its smelter at Herculaneum.

October 11, 2010 - The U.S. Environmental Protection Agency, the U.S. Justice Department and the Missouri Department of Natural Resources on Oct. 8 announced that Doe Run Resources Corp. of St. Louis, North America’s largest lead producer, has agreed to spend approximately $65 million to correct violations of several environmental laws at 10 of its lead mining, milling and smelting facilities in southeast Missouri.

The settlement also requires the company to pay a $7 million civil penalty.

“For years families with children near Doe Run’s facilities have been exposed to unacceptable levels of lead, one of the most dangerous neurotoxins in the environment,” said Cynthia Giles, assistant administrator for EPA’s Office of Enforcement and Compliance Assurance. “Infants and young children are at the greatest risk from lead exposure, which even at low levels can cause behavioral problems, learning deficits and lowered IQ. [The] settlement requires Doe Run to take aggressive actions to clean up their act and work to ensure that families living near the company’s facilities are protected from lead poisoning and other harmful pollution.”

“This settlement will reduce lead pollution in the town of Herculaneum and in other southeastern Missouri communities, as well as encourage the development of innovative technology and projects to improve the environment in impacted communities,” said Ignacia S. Moreno, assistant attorney general of the Justice Department's Environment and Natural Resource Division. “It should also send a message to all companies that handle hazardous waste, such as lead: You must comply with the laws that are intended to protect public health and the environment.”

Instead of installing pollution control technologies to reduce sulfur dioxide and lead emissions at its aging Herculaneum lead smelter, Doe Run has made a business decision to comply with its Clean Air Act obligations and shut down of the smelter by Dec 31, 2013. The company will also provide an initial $8.14 million in financial assurance to guarantee cleanup work at the Herculaneum facility.

The closing of the Herculaneum smelter is expected to result in significant benefits to public health and the environment by annually reducing at least 101,000 tons of carbon dioxide, 22 tons of carbon monoxide, 2.5 tons of volatile organic chemicals, 23 tons of particulate matter, 13.5 tons of nitrogen oxides, 42,000 tons of sulfur dioxide and 30 tons of lead. These reductions will result in significant health and environmental benefits to the Herculaneum and St. Louis areas, which are currently violating federal air standards for lead, ozone and particulate matter.

As part of the settlement, Doe Run will pay a civil penalty of $7 million for violating a series of environmental laws, including the federal Clean Air Act, Clean Water Act, Resource Conservation and Recovery Act, Emergency Planning and Right-to-Know Act, Comprehensive Environmental Response, Compensation and Liability Act (known as Superfund), and the Missouri Air Conservation Law, Clean Water Law, and Hazardous Waste Management Law. The penalty will be paid by Doe Run in a $3.5 million payment to the United States, and a $1.5 million payment to the State of Missouri, with an additional $1 million plus interest to be paid to the state each year for the next two years.

The settlement also requires Doe Run to establish financial assurance trust funds, at an estimated cost of $28 million to $33 million, for the cleanup of Herculaneum and the following active or former mining and milling facilities: Brushy Creek, Buick, Fletcher, Sweetwater, Viburnum, and West Fork. Doe Run will also take steps to finalize and come into compliance with more stringent Clean Water Act permits at 10 of its facilities, including Herculaneum, Glover, Buick mill, Brushy Creek, Fletcher, Sweetwater, Viburnum, West Fork, Mine #35 (Casteel), and Buick Resource Recycling, and will spend an estimated $5.8 million on stream mitigation activities along 8.5 miles of Bee Fork Creek, an impaired waterway near Doe Run’s Fletcher mine and mill facility.

The company will also spend $2 million on community mitigation projects over the next four years. At least $1.1 million of this amount will be spent on diesel engine retrofits, school science lab clean outs, school energy efficiency projects, and installations of heat pumps. Other projects, such as the purchase of sulfur dioxide allowances, wastewater infrastructure projects for the City of Herculaneum, or the development and improvement of environmental management systems at Doe Run’s facilities may also be included.

In addition to the consent decree, EPA is issuing for public comment a new administrative order that requires Doe Run to sample residential properties within 1.5 miles of the Herculaneum smelter and clean up all residential properties with lead soil concentrations of 400 parts per million or higher within that zone. The order requires Doe Run to conduct a final round of soil sampling and residential property cleanups in Herculaneum after the smelter is shut down.

EPA is also issuing for public comment a modified May 2007 administrative order addressing issues related to the transportation of lead-bearing materials between Doe Run facilities. The modified order requires Doe Run to spend an estimated $3.2 million to improve the washing and inspection of its trucks, conduct additional sampling of soil from residential properties along the haul routes, provide independent auditing of its washing and inspection activities, and conduct a study to assess and improve its transportation and handling operations.

The civil judicial consent decree is subject to a 30-day public comment period and approval by a court before it becomes final. Each of the two administrative orders are subject to similar but separate 30-day public comment periods before they become final.

MTPD - Metric Tonne per Day           STPD - Short Ton per Day
MTPA - Metric Tonne per Annum      STPA - Short Ton per Annum
SA - Single Absorption
DA - Double Absorption
 

* Coordinates can be used to locate plant on Google Earth