Knowledge for the
Sulphuric Acid Industry
![]()
Sulphuric Acid on the Web
Introduction
General
Equipment Suppliers
Contractor
Instrumentation
Industry News
Maintenance
Acid
Traders
Organizations
Fabricators
Conferences
Used
Plants
Intellectual
Propoerty
Acid
Plant Database
Market
Information
Library
Technical Manual
Introduction
General
Definitions
Instrumentation
Plant Safety
Metallurgial
Processes
Metallurgical
Sulphur Burning
Acid Regeneration
Lead Chamber
Technology
Gas Cleaning
Contact
Strong Acid
Acid Storage
Loading/Unloading
Transportation
Sulphur
Systems
Liquid SO2
Boiler Feed Water
Steam Systems
Cooling Water
Effluent Treatment
Utilities
Construction
Maintenance
Inspection
Analytical Procedures
Materials of Construction
Corrosion
Properties
Vendor Data
DKL Engineering, Inc.
Handbook of Sulphuric Acid Manufacturing
Order
Form
Preface
Contents
Feedback
Sulphuric Acid
Decolourization
Order Form
Preface
Table of Contents
Process Engineering Data Sheets - PEDS
Order
Form
Table of Contents
Introduction
Bibliography of Sulphuric Acid Technology
Order Form
Preface
Contents
Acid Plant Database October 18, 2010
| Owner | The Doe Run Company |
|
||
| Location |
881 Main Street Herculaneum, Missouri 63048 USA |
|||
| Background |
Formerly - St. Joseph Lead Company (St. Joe Minerals Corp.) - Doe Run Corp. formed by a joint venture between St. Joseph Lead Co. and Homestake Mining (AMAX Lead Company of Missouri, Manger for AMAX-Homestake Lead Trollers) - The Renco Group purchased Doe Run in 1994 |
|||
| Website | www.doerun.com | |||
| Plant | Herculaneum Smelter | |||
| Coordinates | 38º 15' 37" N, 90º 22' 37" W | |||
| Type of Plant | Metallurgical | |||
| Gas Source |
Lead (Pb) Sinter Machine |
|||
| Plant Capacity | 180 MTPD | |||
| SA/DA | 4 SA | |||
| Emissions |
SO2: 20,000 lb/h from all sources (6 lb/h attributed to SO2 sources that do not emit through the main stack) (19,994 lb/h attributed to SO2 sources that emit through the main stack) Sulphuric acid plant tailgas discharges through main stack so acid plant emission is not regulated separately |
|||
| Status | Operating | |||
| Year Built | 1968 | |||
| Technology | Chemical Construction Company - Chemico | |||
| Contractor | Chemical Construction Company - Chemico | |||
| Remarks | - | |||
| Permits |
State of Missouri Department of Natural Resources Facility ID: 099-0003 Part 70 Permit to Operate |
|||
| Permit No. | Issue Date | Expiration Date | Date Modified | |
| OP2006-011B | December 17, 2007 | December 16, 2012 | - | |
| - | - | - | - | |
| Pictures |
|
|||
| General | - | |||
| References | Missouri Permit No. OP2006-011B | |||
| News |
October 11, 2010 - The U.S. Environmental Protection Agency, the
U.S. Justice Department and the Missouri Department of Natural Resources on
Oct. 8 announced that Doe Run Resources Corp. of St. Louis, North America’s
largest lead producer, has agreed to spend approximately $65 million to
correct violations of several environmental laws at 10 of its lead mining,
milling and smelting facilities in southeast Missouri.
The settlement also requires the company to pay a $7 million civil penalty.
“For years families with children near Doe Run’s facilities have been
exposed to unacceptable levels of lead, one of the most dangerous
neurotoxins in the environment,” said Cynthia Giles, assistant administrator
for EPA’s Office of Enforcement and Compliance Assurance. “Infants and young
children are at the greatest risk from lead exposure, which even at low
levels can cause behavioral problems, learning deficits and lowered IQ.
[The] settlement requires Doe Run to take aggressive actions to clean up
their act and work to ensure that families living near the company’s
facilities are protected from lead poisoning and other harmful pollution.”
“This settlement will reduce lead pollution in the town of Herculaneum and
in other southeastern Missouri communities, as well as encourage the
development of innovative technology and projects to improve the environment
in impacted communities,” said Ignacia S. Moreno, assistant attorney general
of the Justice Department's Environment and Natural Resource Division. “It
should also send a message to all companies that handle hazardous waste,
such as lead: You must comply with the laws that are intended to protect
public health and the environment.”
Instead of installing pollution control technologies to reduce sulfur
dioxide and lead emissions at its aging Herculaneum lead smelter, Doe Run
has made a business decision to comply with its Clean Air Act obligations
and shut down of the smelter by Dec 31, 2013. The company will also provide
an initial $8.14 million in financial assurance to guarantee cleanup work at
the Herculaneum facility.
The closing of the Herculaneum smelter is expected to result in significant
benefits to public health and the environment by annually reducing at least
101,000 tons of carbon dioxide, 22 tons of carbon monoxide, 2.5 tons of
volatile organic chemicals, 23 tons of particulate matter, 13.5 tons of
nitrogen oxides, 42,000 tons of sulfur dioxide and 30 tons of lead. These
reductions will result in significant health and environmental benefits to
the Herculaneum and St. Louis areas, which are currently violating federal
air standards for lead, ozone and particulate matter.
As part of the settlement, Doe Run will pay a civil penalty of $7 million
for violating a series of environmental laws, including the federal Clean
Air Act, Clean Water Act, Resource Conservation and Recovery Act, Emergency
Planning and Right-to-Know Act, Comprehensive Environmental Response,
Compensation and Liability Act (known as Superfund), and the Missouri Air
Conservation Law, Clean Water Law, and Hazardous Waste Management Law. The
penalty will be paid by Doe Run in a $3.5 million payment to the United
States, and a $1.5 million payment to the State of Missouri, with an
additional $1 million plus interest to be paid to the state each year for
the next two years.
The settlement also requires Doe Run to establish financial assurance trust
funds, at an estimated cost of $28 million to $33 million, for the cleanup
of Herculaneum and the following active or former mining and milling
facilities: Brushy Creek, Buick, Fletcher, Sweetwater, Viburnum, and West
Fork. Doe Run will also take steps to finalize and come into compliance with
more stringent Clean Water Act permits at 10 of its facilities, including
Herculaneum, Glover, Buick mill, Brushy Creek, Fletcher, Sweetwater,
Viburnum, West Fork, Mine #35 (Casteel), and Buick Resource Recycling, and
will spend an estimated $5.8 million on stream mitigation activities along
8.5 miles of Bee Fork Creek, an impaired waterway near Doe Run’s Fletcher
mine and mill facility.
The company will also spend $2 million on community mitigation projects over
the next four years. At least $1.1 million of this amount will be spent on
diesel engine retrofits, school science lab clean outs, school energy
efficiency projects, and installations of heat pumps. Other projects, such
as the purchase of sulfur dioxide allowances, wastewater infrastructure
projects for the City of Herculaneum, or the development and improvement of
environmental management systems at Doe Run’s facilities may also be
included.
In addition to the consent decree, EPA is issuing for public comment a new
administrative order that requires Doe Run to sample residential properties
within 1.5 miles of the Herculaneum smelter and clean up all residential
properties with lead soil concentrations of 400 parts per million or higher
within that zone. The order requires Doe Run to conduct a final round of
soil sampling and residential property cleanups in Herculaneum after the
smelter is shut down.
EPA is also issuing for public comment a modified May 2007 administrative
order addressing issues related to the transportation of lead-bearing
materials between Doe Run facilities. The modified order requires Doe Run to
spend an estimated $3.2 million to improve the washing and inspection of its
trucks, conduct additional sampling of soil from residential properties
along the haul routes, provide independent auditing of its washing and
inspection activities, and conduct a study to assess and improve its
transportation and handling operations.
The civil judicial consent decree is subject to a 30-day public comment
period and approval by a court before it becomes final. Each of the two
administrative orders are subject to similar but separate 30-day public
comment periods before they become final. |
|||
MTPD - Metric Tonne per Day
STPD - Short Ton per Day
MTPA - Metric Tonne per Annum STPA - Short Ton per
Annum
SA - Single Absorption
DA - Double Absorption
* Coordinates can be used to
locate plant on Google Earth